Hi there!

I'm not from Europe neither live there, do I need to charge and remit VAT to Europe if I choose the "direct to me" payment?
I'm registered as MEI here and as far I know, I don't need to pay any tax other than the "Simples Nacional" monthly.

I'm looking everywhere for this information on internet, but can't really find it.

Thanks in advance.

I don't know where to point you either, but everybody needs to pay VAT on sales to the EU nowadays. If it's too much of a hassle, better let Itch.io collect payments for you.