Well that experience, Julian's backstory, and because I already have 10 romances, which is a lot to juggle. I think his story will still be satisfying overall, though.
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The romanceable characters are Alex, Asher, Dominic, Evan, Griffin, Isaiah, Marco, Matt, Owen, and Riley. I'm not entirely sure what you mean by definitive, but if you're asking if that list will change, the answer is no.
The non-romanceable main characters have their own storylines, but relationship-wise, they'll only be available for hookups.