How can i get the other characters ?
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Have you completed all of the dungeons so far? In order to unlock the Alchemist (the snake) you have to complete the first 2 dungeons and have the story progress to the desert.
The other character to unlock, the Dark Elf Healer, you have to find her in a dungeon and talk to her. She randomly spawns.
The Warrior character will be introduced later along with the Bunny Merchant.