That's the issue, though.... I don't have a video with the same name downloaded. No matter which video I try, they all give the same issue. I tried on many different directories, made sure to triple-check the video file wasn't ANYWHERE near it and still it keeps giving me the error despite the fact the folder is completely empty.....
You'll need to provide more information in that case. Screenshots of your command line, listing of your directories, etc. Also you wrote:
"\G:\JAVs"
Are you sure you want the "\" at the start? Most drive paths start with a letter, like "g:\JAVs" for example. That might be the reason your having issues.