Can't find the crafting for the upper left hand corner of the crafting area.  Also, is Bless equipment slot used at all?

The upper left hand corner is ant hill set, the recipe is in the chest right behind the ant queen.
There is no bless equipment, I forgot to delete it.

Just out of curiosity, is there any other crafting after that, for Valkyrie gear or anything from after exploring the castle that I missed?  I have all the crafting on the left side but only the explosives on the right.  Are those going to be crafting that is added later on?  And I do hope you have more enemies that can devour Noemi as well in that update, I enjoy the ones there are already.