Thank you, that's a good question. Yep, d100 is the correct die. I liked the idea that there was a very small chance that you could take the pill and not die (as if fate didn't want you to have a hero's death). The damage could definitely be scaled down to d20, though, if you wanted it more in line with the poison in the Into the Odd rulebook.
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An adventure for Into the Odd
An adventure for Electric Bastionland
An adventure for Electric Bastionland