Jessica's relationship quest is coming in the second act (after the Reign of Jess) though Poppy's story is likely to be told entirely through her quest line. I'm sorry I don't know what you mean by character 6.
When you go into the Missypedia and press on characters. The character 6 is still not discovered.
Ah, I'm with you. That's Miss Paris, she should have unlocked on the first day. I'll have a look into why she isn't.
