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It can vary enormously from table to table depending on your group's vision, which I realize isn't a terribly helpful answer. If we were doing like, the most stock and straightforward xianxia system possible, it would go like:
Realm 0: Qi Condensation
Realm 1: Foundation Establishment
Realm 2: Golden Core
Realm 3: Nascent Soul
Realm 4+: who knows
If I had to phrase it as generically and setting-agnostically as possible, I guess it would probably be like:
Realm 0: Minor supernatural feats; fights will involve one or two techniques at most, unleashed at critical moments.
Realm 1: You are a wielder of supernatural power. Conflicts become exchanges of spell arts.
Realm 2: You are capable of larger-scale miracles and sustained magical exertion. You have largely transcended mortal frailties.
Realm 3: You are an arch-wizard, capable of prodigious supernatural feats and only barely human anymore.
Realm 4: You are a demigod.
Realm 5: You are a god.
Realm 6: You are a cosmic sovereign, treading stars to dust beneath your feet and ruling over hundreds of worlds.

That's very helpful, thank you! And while I'm at it, how do you reckon would be a good way to handle a Heavenly Tribulation using your system?

I'd probably do it as a special kind of mission, sort of like a Major Entanglement. Smack em in a desperate position, mission objective "survive", etc.