Cloe and gwen, can they get pregnant?
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Nope. Probably won't for quite a bit.
I'd say they're in the same bag as Morgana and Chastity, we need to progress the main story to get to them, so that's probably reserved for act 3.
For now, the only characters that can get pregnant are:
Kana, Pixie, Lily, Jessica, Madison, Veronica, Annie, Asteria, Emma and Luna.
Lyx isn't there yet, and I'm not sure if she'll get there soon or not.
Also Qarinah and Roxy can't get pregnant despite being at 4 hearts, but they explain why if you ask them.