It's untested but if it's a dualshock 3 then it should work with BetterDS3: http://betterds3.ciebiera.net/ as it can bind it to virtually any input device including Xinput and mouse/keyboard. If it's a dualshock 4 then it should work with DS4Windows: http://ds4windows.com/ as it emulates an xbox360 controller.
If you have tried it, I would love to know how well it works as I don't have either controller available to test it on. However, assuming it works, any controller button prompts may be incorrect.