Kinda? I had PC who bagged the Admirer's Admirer by dumb luck lol! She was at the quad party and the A.A. was already in the group she was mingling with before I knew who she was. I got her at high friendship and romance, asked her out and they started dating.
I can't tell you which version of the game it was when I did this, but if you want to hatefuck/bootycall you can try to get their number early on before they really start to hate you.